Synthesis and Transformations of 5-Chloro-2,2′-Dipyrrins and Their Boron Complexes, 8-Chloro-BODIPYs
نویسندگان
چکیده
منابع مشابه
5-Chloro-8-hydroxyquinolinium nitrate
The 5-chloro-8-hydroxy-quinolinium cation in the the title ion pair, C(9)H(7)ClNO(+)·NO(3) (-), is approximately coplanar with the nitrate anion [dihedral angle = 16.1 (1)°]. Two ion pairs are hydrogen bonded (2 × O-H⋯O and 2 × N-H⋯O) about a center of inversion, generating an R(4) (4)(14) ring.
متن کاملsynthesis and characterization of some new cyclometalated organoplatinum(ii) complexes containing phosphite ligand
در این تحقیق روشی جهت سنتز یک سری از کمپلکس های پلاتین (ii) حاوی لیگاند های دهنده ی فسفری شامل فسفیت و فسفین ارائه شده است. واکنش پیش ماده ی پلاتین (ii)،trans/cis- [ptcl2(sme2)2] ، با 2 اکی مولار از لیگاند p(oph)3در حلال بنزن کمپلکس1، cis-[ptcl2(p(oph)3)2] را تولید می نماید. جهت سنتز کمپلکس سایکلو متال فسفیتی، کمپلکس 1 با 1 اکی والان واکنشگر ptcl2 در حلال زایلن در شرایط رفلاکس زیر گاز آرگون م...
synthesis and characterization of potentially biological active cyclometallated organoplatinum(ii) complexes
this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...
15 صفحه اولSynthesis of chloro pyrazolone derivatives and their biological activities
3-Methyl-5-chloro-1-phenylpyrazol and its derivatives were prepared by the reaction with 3methyl -1-phenylpyrazol-5-one, phosphorous oxytrichloride and N-N dimethyl aniline respectively using catalyst. These compounds were further treated with alcohols and sodium hydroxide to form ether linkage. Ethyl acetoacetate reacted with phenylhydrazine at reflux temprature to give 3-methyl-1phenylpyrazol...
متن کامل8-Chloro-2-methylquinoline
In the title compound, C(10)H(8)ClN, the crystal packing shows π-π stacking between the heterocyclic ring and the aromatic ring, with a centroid-centroid distance of 3.819 Å. The crystal studied was a racemic twin, the ratio of the twin components being 0.65 (7):0.35 (7).
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2014
ISSN: 0947-6539
DOI: 10.1002/chem.201304310